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Beilstein J. Org. Chem. 2019, 15, 2069–2075, doi:10.3762/bjoc.15.204
Graphical Abstract
Figure 1: Structures of lilolidine, tivantinib and tarazepide.
Scheme 1: Access to α- and β-arylated lilolidine derivatives.
Scheme 2: Synthesis of α-arylated lilolidine derivatives.
Scheme 3: Synthesis of α,β-di(hetero)arylated lilolidine derivatives.
Scheme 4: Synthesis of α,β-diarylated lilolidine derivatives via successive direct arylations.
Scheme 5: Synthesis of 5,6-dihydrodibenzo[a,c]pyrido[3,2,1-jk]carbazoles via successive direct arylations.